Low equivalent weight ionomer

ABSTRACT

An ionomer and a process for forming the ionomer such that the ionomer has (1) low equivalent weight (below 950, preferably between 625 and 850, and most preferably between 675 and 800) and (2) high conductivity (greater than 0.13 S/cm). In another embodiment, the invention is an ionomer having (1) low equivalent weight (below 950, preferably between 625 and 850, and most preferably between 675 and 800) and (2) acceptably low hydration (less than about 120 weight percent). These ionomers are capable of being processed into thin film and are extremely well-suited for low humidity or high temperature fuel cell applications.

FIELD OF THE INVENTION

[0001] This invention relates to fluorinated ionomers, and specifically to fluorinated ionomers of low equivalent weight that have relatively low hydration that can be processed into thin films. The fluorinated ionomers are preferably perfluorinated compounds suitable for applications where reasonably high ionic conductivity in low humidity environments is desirable. One such application is in solid polymer electrolyte fuel cells.

BACKGROUND OF THE INVENTION

[0002] Solid polymer ionic membranes or films have been well known in the art for many years. These polymers are typically characterized by high ionic conductivity, i.e., rapid transport of ionic species, for example, protons. Additionally, it is desirable for such ionically conducting polymers to be made in the form of membranes or thin films. In so doing, the resistance to ionic transport, which is a function of the film thickness, can be reduced. Fluoropolymer compositions are particularly desirable for such uses, and are disclosed, for example, in U.S. Pat. No. 3,282,875, U.S. Pat. No. 4,358,545 and U.S. Pat. No. 4,940,525.

[0003] The instant invention relates to ionomers, which as used herein means a perfluorinated polymer containing acid groups or acid derivatives easily converted to acid groups such that the acid form of the polymer in membrane form has a room temperature ionic conductivity greater than 1×10⁻⁶ S/cm. As used herein the acid form of an ionomer means that substantially all the ion exchange groups, e.g., SO₃ ⁻ or sulfonic groups, are protonated. One important parameter used to characterize ionomers is the equivalent weight. Within this application, the equivalent weight (EW) is defined to be the weight of the polymer in acid form required to neutralize one equivalent of NaOH. Higher EW means that there are fewer active ionic species (e.g., protons) present. If it takes more of the polymer to neutralize one equivalent of hydroxyl ions there must be fewer active ionic species within the polymer. Because the ionic conductivity is generally proportional to the number of active ionic species in the polymer, one would therefore like to lower the EW in order to increase conductivity.

[0004] Lowering the equivalent weight has previously not been a practical approach to making useful membranes. This is because with fluoropolymers currently known, as the equivalent weight goes down, the amount of water (or solvent) that the polymer absorbs goes up. The amount of water absorbed by the polymer is called the degree of hydration or hydration. It is expressed as the weight percent of water absorbed by the polymer under a given set of conditions, for example, after immersion in room temperature water for two hours. A higher degree of hydration is desirable up to a point because it tends to increase the ionic conductivity of the membrane. Correspondingly, lowering the degree of hydration has traditionally meant decreasing the conductivity. But there is a limit to the amount of water or solvent such fluoropolymer membranes can contain. If too much water is present, the film may lose much of its physical integrity, becoming gel-like with little or no rigidity. In the extreme, the polymer may completely disintegrate. In addition, depending on the exact polymer composition, low EW fluoropolymer ionomers may even partially or completely dissolve in water. Furthermore, even if the films were stable, too high a hydration would tend to dilute the number of ions present for conduction, thereby lowering the ionic conductivity. Thus, there is an optimal degree of hydration that is high enough to provide the highest possible conductivity, while not so high that the films become physically unstable when hydrated.

[0005] Thus, one would like to decrease the equivalent weight of these fluoropolymers to increase their conductivity, but heretofore could not practically do so because the degree of hydration and/or water solubility was too high to form practical membranes.

[0006] Various approaches have been used to circumvent this limitation. In U.S. Pat. No. 5,654,109, U.S. Pat. No. 5,246,792, U.S. Pat. No. 5,981,097, U.S. Pat. No. 6,156,451, and U.S. Pat. No. 5,082,472 various forms of layered composite membranes are suggested. In '109, the use of a bilayer or trilayer composite ion exchange membranes is suggested where the outer layer or layers are lower equivalent weight for improved electrical performance, while the core layer has a higher EW that provides strength. A similar approach is suggested in '792, but the films are layers are characterized by their glass transition temperatures instead of EW. Three or more layers with variable ion exchange ratio (a parameter proportional to EW) are proposed in '097. In '472 a process to form a membrane is taught whereby a perfluorinated ionomer is laminated to a porous expanded PTFE membrane, followed by impregnation of a low equivalent weight ionomer (e.g., 920-950 EW) into that laminate. Because the impregnation is performed with a solution with low solids content (e.g., 2%), the amount of low equivalent weight material in the final product is relatively low. Although each of these approaches may offer some improvement over the a monolithic single layer fluoropolymer membrane, they all involve the use of rather complex, composite, multilayer structures that can be difficult and/or expensive to process.

[0007] Approaches to modifying the fluoropolymer itself have also been taught, for example in U.S. Pat. No. 4,358,545 to Ezzell. The properties of these polymers are described in Moore and Martin, “Morphology and Chemical Properties of the Dow Perfluorosulfonate Ionomers”, Macromolecules, vol. 22, pp. 3594-3599 (1989), and Moore and Martin, “Chemical and Morphological Properties of Solution-Cast Perfluorosulfonate Ionomers”, Macromolecules, vol. 21, pp. 1334-1339 (1988). The approach described in these references is to produce ionomers with shorter side chains along the polymer backbone. This approach is particularly desirable for use in coating processes (for example, as described in U.S. Pat. No. 4,661,411 and U.S. Pat. No. 5,718,947) but still suffers limitations for use as fluoropolymer ionomer membranes. In particular, these polymers can still be difficult to form into acceptably thin, strong membranes from solution.

[0008] Another approach as described by various authors is to form co-polymers of tetrafluoroethylene and ionomers using variations of the well-known emulsion polymerization (for example, the process disclosed in U.S. Pat. No. 3,282,875). In U.S. Pat. No. 5,608,022 to Nakayama et. al. and WO 00/52060 to Bekarian, et. al., processes are taught to form functionalized, fluorinated co-polymers by dispersing fine droplets of a fluorinated co-monomer before polymerizing with a traditional fluorine containing monomer, e.g. tetrafluoroethylene. In these processes, the formation of fine droplets of the co-monomer is a key to a successful preparation of the polymer. In WO 94/03503 to Barnes, et. al. the rate of addition of the tetrafluoroethylene monomer to the ionomer emulsion is controlled by either altering the concentration of the emulsion during polymerization, varying the pressure of the tetrafluoroethylene gas during reaction, or varying the agitation of the reaction mixture. Barnes teaches that these approaches result in a product with higher utilization of the ionomer as determined by the property of equivalent weight distribution, which he defines as a ratio of EW determined by means of titration to that determined by nuclear magnetic resonance. Barnes et. al. claims that this higher utilization leads to a higher Relative Hydration Product and higher Specific Conductivity. Both these parameters were evaluated in the presence of 2.5 Molar sulfuric acid (2.5 M H₂SO₄), and therefore are not relevant to the current application where only hydrated polymer in the presence of water is considered.

[0009] In yet another approach taught in PCT WO 00/79629 an ionomeric polymer is intimately mixed with a structural film-forming polymer, such as a terpolymer of tetrafluoroethylene, hexafluoropropylene and vinylidene fluoride (e.g., THV series available from Dyneon Corp., Oakdale, Minn.). It then is possible to form acceptably thin films using low equivalent weight ionomers. But, the degree of hydration is still relatively high, 80-110%, when 800 EW starting ionomer is used (e.g., Table 1 in WO 00/79629). Thus, these films might be expected to be relatively weak because of the high hydration.

[0010] Finally there is also a large body of art that describes approaches to forming non-ionomeric fluoropolymers. For the most part, this art is not relevant to the instant invention described here because the products produced do not have substantial ionic conductivity, i.e., the ionic conductivity of these products is less than about 1×10⁻⁶ S/cm at room temperature.

[0011] Fluoropolymer ionically conducting membranes have been utilized in many different applications. One application that has been widely suggested is as electrolytic cell membranes for the electrolysis of sodium chloride as disclosed, for example, in U.S. Pat. No. 4,358,545, 4,417,969, and 4,478,695. Additionally, this generic class of polymers, described as fluoropolymer ionomers, have been proposed for use as coatings as described above in US. Pat. No. 4,661,411 to Martin et.al.; as wire insulation (e.g., in WO 90/15828); as replacements for acid catalysts, primarily in organic synthesis as described in “Perfluorinated Resin sulfonic Acid (Nafion-H (R)) Catalysis in Synthesis”, by Olah, G. A., Iyer P. S. and Surya P. G. K., in Journal: Synthesis (Stuttgart), 1986 (7) 513-531, and in “Perfluorinated Resin sulfonic acid (Nafion-H) Catalysis in Organic Synthesis” by Yamato, T., in Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, volume 53, number 6, June 1995, p 487-499; as a membrane for water electrolysis as described in Yen, R. S., McBreen, J., Kissel, G., Kulesa, F. and Srinivasan, S. in the Journal of Applied Electrochemistry, volume 10, pg. 741, 1980; as a membrane for electrowinning as described, for example, in “The Use of Nation-415 Membrane in Copper Electrowinning from Chloride Solution” by Raudsepp, R., and Vreugde, M., in CIM Bulletin, 1982, V75, N842, P122; in metal ion recovery systems as described in product literature of Nafion® perfluorinated membrane case histories, DuPont Company, Polymer Products Department, Wilmington, Del. 19898; as a tube to continuously and very selectively dry wet gas streams (see product literature from Perma Pure, Inc., Toms River, N.J.); and as components in polymer electrolyte membrane (PEM) fuel cells. In the latter case, they can function both as the electrolyte or a component thereof, for example as described in by Bahar et.al. in U.S. Pat. Nos. 5,547,551 and 5,599,614; and/or as a component in one or both of the electrodes of the MEA.

[0012] When the ion conducting polymers, or ionomers, are used as the electrolyte in PEM fuel cells they conduct protons from one electrode to the other. A common problem associated with such fuel cells is that contaminants such as carbon monoxide tend to poison the catalysts used in the MEA. These contaminants can interfere with the flow of ions between the electrodes and thus degrade the performance of the fuel cell.

[0013] One way to reduce the effect of carbon monoxide is to operate the fuel cell at an elevated temperature. This reduces the formation and/or increases the destruction rate of potential contaminants and thereby allows more efficient electrode performance.

[0014] The problem with running at high temperatures, however, is that it vaporizes liquid water within the fuel cell, and in so doing, tends to reduce the degree of hydration in the membrane. As described above, decreasing the hydration lowers the ionic conductivity, thereby reducing the efficiency of ion transport through the membrane and adversely affecting fuel cell operation. In fact, at lower temperatures, in PEM fuel cells using conventional ionomers, the incoming gas streams are usually well-humidified in order to maintain a relatively high degree of hydration. Only by adding the additional water in the form of humidity in the gases can the hydration be kept high enough to allow efficient fuel cell operation for long periods of time. However, as the temperature gets close to, or above, the boiling point of water this approach becomes difficult and inefficient. Thus, an ionomer with relatively low hydration and acceptably high ionic conductivity would require less ambient water to function as the electrolyte in PEM fuel cells. It could function efficiently both in lower humidity environments at lower temperatures, as well as at temperatures closer to and even potentially above the boiling point of water.

[0015] As described above, the known low equivalent weight ionomers have a relatively high hydration. They are also known to be partially or completely soluble in water as well. These factors would counsel against their use in environments where water is produced, e.g. hydrogen-oxygen fuel cells, because these polymers tend to become physically unstable in these environments. In addition, as described above and shown recently (WO 00/52060, Table 1) the ionic conductivity decreases as the equivalent weight goes down concomitant with a large increase in hydration. The ionic conductivity reported in WO '060 decreases by more than 30% when the equivalent weight of the subject ionomer is reduced from 834 to 785.

[0016] Against this background of conventional wisdom, applicants have discovered a low equivalent weight ionomer that has a combination of relatively high ionic conductivity and relatively low hydration, As a result, this invention makes possible the more effective use of solid fluoropolymer membranes in existing applications such as those described above. Additionally, new applications heretofore not practical may become possible with this new, unique set of characteristics. The instant invention is particularly valuable as an electrolyte or component thereof, or as a component in the electrode of polymer electrolyte membrane fuel cells operating at high temperatures or low humidities.

SUMMARY OF THE INVENTION

[0017] The present invention is an ionomer and a process for forming the ionomer such that the ionomer has (1) low equivalent weight (below 950, preferably between 625 and 850, and most preferably between 675 and 800) and (2) high conductivity (greater than 0.13 S/cm). In another embodiment, the invention is an ionomer having (1) low equivalent weight (below 950, preferably between 625 and 850, and most preferably between 675 and 800) and (2) acceptably low hydration (less than about 120 weight percent). These ionomers are capable of being processed into thin film and are extremely well-suited for low humidity or high temperature fuel cell applications.

BRIEF DESCRIPTION OF THE DRAWING

[0018]FIG. 1 is a schematic of a room temperature conductivity fixture.

[0019]FIG. 2 is a schematic of a high temperature conductivity cell.

[0020]FIG. 3 is a plot of the conductivity plotted against ionomer equivalent weight of an exemplary embodiment of the inventive ionomer compared to the conductivity of prior art samples.

[0021]FIG. 4 is a plot of degree of hydration plotted against ionomer equivalent weight of an exemplary embodiment of the inventive ionomer compared to the degree of hydration of prior art samples.

[0022]FIG. 5 is a cross-sectional view of a membrane formed from an ionomer according to an exemplary embodiment of the present invention.

[0023]FIG. 6 is a cross-sectional view of a composite membrane formed using an ionomer according to an exemplary embodiment of the present invention.

[0024]FIG. 7 is a cross-sectional view of a membrane electrode assembly formed using an ionomer according to an exemplary embodiment of the present invention.

[0025]FIG. 8 is a cross-sectional view of a fuel cell including an ionomer according to an exemplary embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0026] In this invention, an aqueous mini-emulsion polymerization procedure is described for producing a co-polymer of two or more monomers. The co-polymer comprises a substantially fluorinated backbone and one or more ionomers, such that the product has unusually high room temperature ionic conductivity. The polymerization is carried out in the presence of a mini-emulsion of a liquid perfluorinated hydrocarbon that is a saturated aliphatic or aromatic organic compound optionally containing oxygen, nitrogen, or sulfur atoms and having a molecular weight preferably below 2000. The polymer particles so produced can be formed into thin membranes that have unusually high room temperature ionic conductivity when converted to the acid form, greater than about 0.13 S/cm, and preferably greater than about 0.20 S/cm.

[0027] The process used herein is generally known in the art as mini-emulsion polymerization, as described for example in Chapter 20, Miniemulsion Polymerization by E. David Sudol and Mohamed S. El-Aasser, in Emulsion Polymerization and Emulsion Polymers, P. A. Lowell and M. S. El-Aasser, eds, John Wiley and Sons, Ltd, New York, 1997. In these processes, a mini-emulsion, which is defined herein by a droplet size in an emulsion between 50 and 500 nm, is formed by subjecting an oil (herein an ionomer)/water/surfactant/co-surfactant system to high shear mixing such as that produced by an ultrasonifier, a Manton Gaulin homogenizer, or a microfluidizer. This mini-emulsion is then subjected to a polymerization reaction. The processes and products produced from these processes in the present invention are substantially different than prior art, e.g., that described in U.S. Pat. No. 5,608,022 to Nakayama et. al., and WO 00/52060 to Bekarian, et. al, because of the presence of the co-surfactant. The use of a co-surfactant to aid in achieving a mini-emulsion offers the advantage of using lower quantities of the surfactant, which can be advantageous because high concentrations of the surfactant may have detrimental effects on the final product.

[0028] Although the use of a co-surfactant in microemulsion polymerization of fluoropolymers has been recognized in the art (e.g., see Wu et.al. in U.S. Pat. No. 6,046,271) the use of the a mini-emulsion process with a co-surfactant for the preparation of ionomeric polymers described herein is novel. For example, in '271 Wu discloses a polymerization procedure of forming a microemulsion of at least one liquid perfluorinated hydrocarbon compound; adding at least one gaseous free-radical polymerizable polymer to the microemulsion; and initiating polymerization by adding a free radical initiator to the mixture. Wu did not anticipate the use of ionomeric monomers with acid end groups described herein. The particularly surprising result we have discovered is that using ionomeric monomers in a mini-emulsion polymerization in the presence of a co-surfactant (instead of the micro-emulsion of straight chain alkenes disclosed previously), we are able to produce polymers that have unusually high ionic conductivity. This totally unexpected result, coupled with equally surprising relatively low hydration of the resulting polymer, allow the production of ion conducting membranes of great value.

[0029] The co-surfactants can be chosen from among those co-surfactants known in the art, such as alcohols, amines or other amphiphilic molecules, or salts. Single or multiple co-surfactants can be employed to facilitate formation of the mini-emulsion. A particularly preferable co-surfactant is one drawn from the class of perfluorinated hydrocarbons used herein as a co-surfactant is a low molecular weight compound that is liquid at the temperature at which polymerization is carried out. The molecular weight is preferably less than 2000. The perfluorinated hydrocarbon preferably has a boiling point less than 300 degrees C. It can also be a perfluorinated aromatic compound such as perfluorinated benzene; a perfluorinated alkyl amine such as a perfluorinated trialkyl amine; a perfluorinated cyclic aliphatic, such as decalin or perfluoro tetradecahydrophenanthrene; or a heterocyclic aliphatic compound containing oxygen or sulfur in the ring, such as perfluoro-2-butyl tetrahydrofuran. Examples of perfluorinated hydrocarbons include perfluoro-2-butyltetrahydrofuran, perfluorodecalin, perfluoromethyidecalin, perfluorodimethyldecalin, perfluoromethylcyclohexane, perfluoro(1,3-dimethylcyclohexane), perfluorodimethyidecahydronaphthalene, perfluorofluoorene, perfluoro(tetradecahydrophenanthrene), perfluorotetracosane, perfluorokerosenes, octafluoronaphthalene, oligomers of poly(chlorotrifluoroethylene), perfluoro(trialkylamine) such as perfluoro(tripropylamine), perfluoro(tributylamine), or perfluoro(tripentylamine), and octafluorotoluene, hexafluorobenzene, perfluoro ethers or perfluorinated polyethers, and commercial fluorinated solvents, such as Fluorinert FC-77 or FC-75 produced by 3M. The fluorinated alkanes can be linear or branched, with a carbon atom number between 3 and 20. Oxygen, nitrogen or sulfur atoms can also be present in the molecules.

[0030] The fluorinated surfactant has the structure R_(g) E X, where R_(g) is a fluorinated alkyl or a fluorinated polyether group with a carbon number between 4 and 16, E is an alkylene group with a carbon number between 0 and 4, and X is an anionic salt such as COOM, SO₃M, SO₄M, a cationic moiety such as quarternary ammonium salt, or an amphoteric moiety such as aminoxide, or a non-ionic moiety such as (CH₂CH₂O)_(m)H; and M is H, Li, Na, K, or NH₄—; and m is a cardinal number of 2 to 40. One preferred fluorinated surfactant is ammonium perfluoro octanoate.

[0031] The substantially fluorinated backbone of this invention can be a polymer prepared from a number of different monomers or co-monomers that have a high fluorine concentration. These can include, but are not limited to tetrafluoroethylene, and mixtures of tetrafluorethylene with one or more monomers selected from the group hexafluoropropylene, vinyledene fluoride, chlorotrifluoroethylene, perfluoropropylvinyl ether, perfluoromethylvinyl ether and ethylene. One preferred monomer used to form the substantially fluorinated backbone is tetrafluoroethylene.

[0032] The ionomeric monomers used in the polymerization reaction are substantially fluorinated organic compounds containing at least one moiety that has ionic functionality and at least one polymerizable group. Alternatively, the molecule may carry precursors that can be converted into ionic functionality after the polymerization process is complete. Examples of monomers suitable for forming these ionomers include compounds having the formula

[0033] and the like which after polymerization forms pendant groups on the substantially fluorinated backbone of the form

[0034] In the above, X is F, Cl or Br or mixtures thereof; n is an integer equal to one or two; R_(f) and R_(f′) are independently selected from the group of F, Cl, perfluoroalkyl radical, and chloroperfluoroalkyl radical; Y is an acid group or a functional group convertible to an acid group; a is zero or an integer greater than zero; and b is an integer greater than zero. Examples of Y as acid groups include, but are not limited to, sulfonic acid or its salt form, —SO₃Z; sulfonamide, —SO₂N(R₁)—; sulfonimide, —SO₂N(R₁)SO₂R₂; carboxylic acid, —CO₂Z; phosphonic acid —PO(OR₁)₂ and the like; wherein Z is H, or any combination of cations including, but not limited to, ammonium ion, metallic ions; or organoammonium ions; R₁ is H, an alkyl group with carbon number from 1 to 10, or a partially fluorinated alkyl group with a carbon number of 2-10; and R₂ is a perfluorinated alkyl chain with carbon number from 1 to 8, which can optionally contain oxygen or other atoms or groups that are stable to free radicals; or a perfluoroalkyl group, which can also optionally contain oxygen or other atoms or groups that are stable to free radicals and is terminated with Y as it is defined above. Examples of Y that are function groups convertible to an acid group include, but are not limited to, sulfonyl halide, —SO₂W; ester, —COOR; and the like, wherein W is F, Cl, or Br, and R is an alkyl group with carbon number from 1 to 20. One preferred ionomeric monomer is CF₂═CF—O—CF₂CF(CF₃)—O—CF₂CF₂—SO₂F that forms pendant groups having the formula, —O—CF₂CF(CF₃)—O—CF₂CF₂—SO₂F.

[0035] The preparation of the mini-emulsion depends on careful selection of the ingredients. The mini-emulsion is prepared by mixing water, perfluorinated hydrocarbon, fluorinated surfactant(s), ionomer, and a co-surfactant or inorganic salts. The amounts employed are 0.1-40 weight percent, preferably 0.1-20, of the perfluorinated hydrocarbon; 1-40 weight percent, preferably 0.1-25, of the surfactant and cosurfactants; 1-20 weight percent, preferably 5-15, of the ionomer; with the remainder water. This mixture is subjected to high shear mixing using methods known in the art such as mechanical shear and/or cavitation to break the oil phase into submicron size droplets. Multiple passes through such mixers may be required to obtain a mini-emulsion. The resulting mini-emulsion is neither completely transparent as observed with microemulsions, nor milky white as it is in a (macro)emulsion. Rather, it is substantially translucent, often with a slight hint of color, for example a blue tint. Without being bound by any particular theory, the resulting mini-emulsion of perfluorinated hydrocarbons is believed to serve as mini-reactors for fluorinated monomers to enter and to be polymerized.

[0036] To initiate polymerization, the temperature of the mini-emulsion is adjusted to between 0 and 150 degrees C., preferably 40 to 100 degrees C. Initiators for polymerization include free-radical initiators, such as persulfates, azo initiators, peroxides, or photo initiators, which can generate free radicals by ultraviolet or gamma rays. Amount of initiators present can range between 0.001 to 5 percent by weight based on the final polymer content. Co-solvents such as an alcohol, amines or other amphiphilic molecules, or salt can be employed if desired to facilitate formation of the mini-emulsion. The fluorinated monomers are introduced to the reactor either in vapor phase or liquid phase into the aqueous liquid. Sufficient mixing between phases is important to encourage mass transfer.

[0037] The product produced from the polymerization is an ion conducting polymer with low equivalent weight and relatively low hydration. The resultant ionomers are nonetheless soluble in organic solvents, which allows them to be formed into thin films, either alone (see film 50 in the exemplary embodiment shown in FIG. 5) or in composites with other substrates to form a composite membrane (see substrate 60 and ionomer 61 forming composite membrane 62 in the exemplary embodiment shown in FIG. 6). Such other substrates may comprise a support of porous material such as expanded polytetrafluoroethylene (ePTFE). As used herein, “porous” means having a plurality of interconnected passages and pathways. Solutions of the ionomer may be impregnated into the porous support by methods known in the art, for example as described in U.S. Pat. Nos. 5,547,551 and 5,599,614 to Bahar et.al.

[0038] Such films are useful as separator membranes in membrane electrode assemblies (MEAs). As shown in the exemplary embodiment shown in FIG. 7, electrodes 70, 71 are adhered or otherwise attached to either side of a membrane 72 to form MEA 73. MEA 73 is in turn useful in a fuel cell 83, as shown in the exemplary embodiment shown in FIG. 8. Gas diffusion media 80 and 81 may optionally be attached or otherwise adhered to the electrodes, and current collectors (not shown) may optionally be connected to positive terminal 84 and negative terminal 85. During operation the fuel enters the cell and reacts at the anode to generate electrons that are collected at negative terminal 85. The electrons flow through an external load (not shown) to the cathode terminal 84. The electrons are used at the cathode together with the oxidizing species. Depending on the type of fuel and the type of oxidizing species, products may be formed in the anode compartment, the cathode compartment or both. If present, these products are swept out of the cell with any excess fuel and/or oxidizing species that may optionally have been used in the inlet gases. In another alternative embodiment, the electrodes in the MEA may also contain the instant invention as one component of a multi-component electrode system. The inventive polymer is also useful in other electrolytic cells.

[0039] The following procedures were used to characterize the ionomers prepared according the above description.

[0040] Average Colloidal Particle Size

[0041] The average colloidal particle size for solutions of the inventive co-polymer solutions prepared herein was determined using a Brookhaven Instrument Corporation (BIC) Laser Light Scattering Submicron Particle Size Analyzer. Samples of the as-prepared co-polymer solutions were diluted with de-ionized water to between 1 and 50% by weight from the original solutions and placed in the standard BIC acrylic square cell. The laser light was incident on the cell at a 90 degree scattering angle. The average particle size as reported by the 90Plus Particle Sizing Software is reported here as the average colloidal particle size.

[0042] Membrane Formation

[0043] For examples below where membranes were required, and prior to the equivalent weight determination described below, the following procedure was followed. The acid form of the polymer was obtained from the sulfonyl fluoride form of the polymer using practices well known in the art. Here, it was generated by completely hydrolyzing the sulfonyl fluoride form of the polymer in KOH and then completely reacidifying in HNO₃. Approximately 2 g of solid ionomer pieces in the acid form weighing ˜0.05 g each were placed in a uniform pile between two sheets of Kapton® polyimide film (DuPont High Performance Materials, Circleville, Ohio). The sandwich of material was placed between the preheated fully open 64 in² platens of a Marsh Instruments PHI pneumatic press. The platen temperature was set such that the temperature reading between the top and bottom platens when in contact with each other was 165° C. The bottom platen was then raised until the upper sheet of Kapton film made contact with the top platen. The ionomer sample was then allowed to sit for 15 minutes. The sandwich was then compressed by cycling the pressure 3-5 times between approximately 1 ton for 10 seconds and approximately zero tons for ten seconds. The pressure was then increased to 5 tons, then slowly increased to 10 tons over a period of 90 to 120 seconds. Finally, the pressure was then increased to 20 tons and the sample was held under 20 tons at 165° C. for 120 seconds to produce a uniform, clear film, typically approximately 5 mil thick.

[0044] Degree of Hydration

[0045] A sample ˜1 cm by ˜1.5 cm in size was cut from a membrane and placed in a vacuum oven at 120 degrees C. for ˜70 hours at ˜3 inches of Hg using a nitrogen bleed to maintain the pressure. The sample was removed, and weighed when cool (˜1 minute or less) to obtain the dry weight. The sample was then placed in deionized water for 2 hours at room temperature. As used herein, room temperature is 23 degrees C. plus or minus two degrees. The sample was removed from water, patted dry with a paper cloth, and immediately weighed to obtain the hydrated weight. The degree of hydration in percent is calculated as ${{Degree}\quad {of}\quad {Hydration}\quad \left( {{in}\quad \%} \right)} = \frac{100*^{\quad}\left\lbrack {{{Hydrated}\quad {Weight}} - {{Dry}\quad {Weight}}} \right\rbrack}{{Dry}\quad {weight}}$

[0046] Four samples for each membrane were tested, and the reported hydration is the arithmetic mean of the four measurements.

[0047] Equivalent Weight

[0048] The method used here to determine equivalent weight takes a measured weight of dried ionomer solid and calculates an acid equivalent weight based on the first inflection point of the titration curve near pH 7. Specifically for each sample, approximately 5 g of solid ionomer pieces weighing no more than 0.05 g each were dried in oven for at least two hours at 80° C. under full vacuum (˜2 in. Hg). The dried pieces were removed from the oven and placed in a capped container in order to minimize moisture pickup. After allowing the dried sample to cool to room temperature in the capped container, approximately 0.15 g was quickly weighed into a 100 ml titration cup. The sample of known dry weight was then allowed to soak in the titration cup for 15 minutes in 5 ml of deionized water and 5 ml of ethanol. To the soaked sample, 55 ml of 2.0N NaCl solution were then added. A back titration method using a TIM900 Titration Manager (Radiometer Analytical S.A., Lyon, France) was then started beginning with the addition of 5 ml of 0.05N NaOH solution. The entire blend was then stirred for 15 minutes under a nitrogen blanket prior to the acid titration with 0.01N HCl solution. The end point near pH 7 was used to calculate both the ion exchange capacity (IEC) and the acid equivalent weight (EW) of the sample according to ${{IEC}\quad \left( {{meq}/g} \right)} = \frac{\left\lbrack {5\quad {ml}\quad {{Na}{OH}} \times 0.05N} \right\rbrack - \left\lbrack {{Volume}\quad {HCI}\quad ({ml}) \times 0.01N} \right\rbrack}{\left. {{Dried}{\quad \quad}{Ionomer}\quad {Solid}\quad {Weight}\quad (g)} \right\}}$

 EW(g/eq)=1000/IEC(meq/g)

[0049] The arithmetic mean of the measured results from two different samples of each membrane is reported as the Equivalent Weight.

[0050] Room Temperature Ionic Conductivity

[0051] A membrane sample about 1.5 inches by about 2 inches in size was first equilibrated at room conditions of 21 degrees C., 61% RH for 24 hrs. It was then immersed into a plastic beaker containing room temperature deionized water. Three measurements were taken over 90 minutes, one every 30 minutes. To take the measurements the membrane sample was taken out of the water and patted dry by paper tissues. The thickness was then measured immediately using an MT12B Heidenhain (Schaumburg, Ill.) thickness gauge attached to a Heidenhain ND281B digital display. The gauge was mounted vertically over a flat plate, and measurements were made at nine different locations on the sample, covering the corners and center of the sample. The spring-loaded probe of the gauge was lowered gently on the film for each measurement to minimize compression. The mean of the nine values was used as the sample thickness. The ionic resistance of the membrane, 11, was then measured using a four-point probe conductivity cell shown in FIG. 1. The sensing probes, 5, of conductivity cell, 10, are approximately one inch long, and approximately one inch apart. A plexiglass spacer 1 provides insulation between the current probes 4 and sensing probes 5. The cell is held together with nylon screws 2 and electrical contact is made to the probes through holes 3. During the measurement, a 500 g weight (not shown) was loaded onto the cell to ensure good contact. It was found that the resistance value is independent of further pressure onto conductivity cell 10. The resistance was measured by connecting leads (not shown) through holes 3 using 10 mV AC amplitude at 1000 Hz frequency applied by a Solartron SI 1280B controlled by ZPlot software written by Scribner Associates. Measurements were taken in the potentiostatic mode. Under these conditions, the phase angle was found to be insignificant throughout the measurement. The room temperature ionic conductivity in S/cm for each measurement was calculated from the formula $\sigma = \frac{L_{2}}{R^{*}{L_{1}}^{*}D}$

[0052] Where σ is the room temperature ionic conductivity, L₂ is distance between the sensing probes, here equal to 2.5654 cm, L₁ is the length of the sensing probe, here 2.5603 cm, D is the measured thickness of the membrane in cm, and R is the measured resistance in ohms. The results showed that the room temperature ionic conductivity was independent of the soaking time between 30 and 90 minutes for all the samples tested. The reported value is the average calculated from the three measurements.

[0053] High Temperature Ionic Conductivity

[0054] The high temperature ionic conductivity at temperatures of 80 and 120 degrees C. was also measured. In this case, the conductivity was measured using a different apparatus where the temperature and relative humidity of the atmosphere could be more precisely controlled. These measurements were performed to confirm that the conductivity of samples soaked in room temperature water and measured at room temperature showed the same trends between materials as samples measured at higher temperature and equilibrated at a fixed relative humidity condition. These measurements are particularly relevant because it is well known that Schröder's paradox [P. Schroder, Z. Physik Chem., Vol. 75, pg. 75 (1903)] is observed in perfluorosulfonic acid type ionomeric membranes [e.g., see T. A. Zawodzinski, T. E. Springer, F. Uribe and S. Gottesfeld, Solid State Ionics, Vol. 60, pg. 199(1993) and G. Blumenthal, M. Cappadonia and M. Lehmann, Ionics, Vol. 2, pg. 102 (1996)]. It is thus expected that the measured conductivity of the inventive membrane will be different when measured in liquid water compared to that measured in 100% relative humidity at the same temperature even though the water activity is, in theory, equal to one in both cases. Therefore, to confirm that the inventive ionomers do indeed have improved conductivity when in equilibrium with water vapor as well as when soaked in liquid water, a high temperature conductivity test was performed where the relative humidity and temperature were controlled.

[0055] This test was performed as follows: three different thicknesses of the sample membrane to be tested were prepared as described above. Two 0.5 inch diameter ELAT® gas diffusion media (GDM) available from E-TEK, Inc. were die cut. Approximately 1 mg/cm² of ionomer prepared according to Example 2 in co-pending application to Wu et. al., was brushed onto the GDM surface, and then placed against an ˜1.5 inch by ˜1.5 inch sample membrane to form a sandwich. This sandwich was then laminated for 3 minutes by applying 15 tons of pressure to ˜18 inch by ˜18 inch platens of a hydraulic press where the top platen was heated to 160 degrees C. After cooling, the GDM/sample/GDM sandwich was placed in the high temperature ionic conductivity apparatus 20 as shown in FIG. 2 for testing.

[0056] The apparatus 20 consists of a split aluminum body 21 with a polytetrafluoroethylene (PTFE) cell 22. Cell 22 is clamped together during operation with an air-actuated pressure of 120 psi. Two electrode leads 23 with 40% porous 316L stainless steel Pt coated pellets 24 welded on the end of the electrode leads 23 enter the cell 22 through the center to form the two electrodes between which the test sample 25 is placed. Test sample 25 comprises sample membrane 26 with GDM 27 on both sides prepared as described above. The bottom electrode lead 23 is attached to an air actuated cylinder (not shown) that can apply a fixed pressure to the bottom electrode lead. A pressure of 150 psi was used for all testing described herein. Nitrogen gas is flowed into the cell through two lines, one for each half of the cell. The humidity of the each inlet gas stream is controlled by flowing the gas through a bottle of water where the temperature is fixed. The gas lines after the each humidification bottle are also heated to prevent condensation. The cell temperature, temperature of the humidification bottles, and gas lines are controlled by a Scribner Associates Membrane Test System (Scribner Associates, North Carolina). The humidity of both inlet gas streams is measured with a Vaisala HM138 humidity probe (Vaisala Group, Vantaa, Finland). For all testing here, the measured humidity of both halves of the cell was the same to within 3-5 percent RH.

[0057] After placing the test sample 25 in the cell, closing it, and applying pressure to the cell and the electrode leads, the cell was heated to the lowest test temperature with flowing dry gas. It was equilibrated under dry gas at that temperature for 30 minutes. Then the humidity was stepped to 10% RH. The frequency for measurements was then determined by measuring the impedance in potentiostatic mode with a frequency sweep from ˜1 Hz to ˜20 kHz using a Solartron 1280B Impedance Analyzer (Solartron Analytical, Hampshire, England). The frequency where the measured phase angle was about zero was determined. This frequency was used in all subsequent measurements. Typically, this frequency was in the range of 7 to 15 kHz. The test sequence was then initiated under computer control whereby the humidity was changed at low temperatures to the following values: about 10,20,40,50,60,80, and 90 percent RH. Impedance measurements at each RH step were recorded at five second intervals until the impedance changed less than 1 milliohm. This steady state impedance (equal to the resistance since the phase angle is zero) was recorded as the cell resistance at that temperature and RH. Then the cell is stepped to a new higher temperature, returned to 10% RH, and the process repeated. For higher temperatures, it was not possible to reach high relative humidities because the cell was not operated under pressure. Therefore, the maximum RH achievable was lower at higher temperatures. In this case, six steps of RH were made between 10% and the maximum achievable RH at that temperature. The RH and temperature are reported here as the average of the two values obtained from the RH and thermocouple probes in each half of the cell.

[0058] In order to remove the effects of interfacial resistances, which can be a significant fraction of the total resistance, the resistance at any given temperature/RH condition was measured for samples of three different thicknesses. These resistances were plotted as a function of thickness, a linear regression fit to the data, and the extrapolated zero thickness resistance value was used as the interfacial resistance for that sample. This value was then subtracted from the measured resistance to obtain the actual sample resistance. The high temperature ionic conductivity was calculated from the formula: $\sigma = \frac{L}{R^{*}A}$

[0059] where L is the thickness of the sample measured before it is placed in the apparatus, and A is the area of the sample in contact with the electrode leads, i.e., pi times the diameter squared divided by 4; and R is the measured resistance reduced by the interfacial resistance determined from the zero thickness extrapolation.

[0060] The following examples are intended to demonstrate but not to limit the inventive compounds and methods of making them.

EXAMPLE 1

[0061] An aqueous mini-emulsion was prepared by pre-mixing and homogenization of a mixture containing 1650 grams of deionized water, and 50 grams of 20% by weight of ammonium perfluoro octanoate (ammonium salt of perfluoro octanoic acid) aqueous solution, and 194 grams of 82.5% by weight of CF₂═CF—O—CF₂CF(CF₃)—O—CF₂CF₂—SO₂F monomer and 17.5% by weight of Fluorinert® FC-77 (a perfluorinated hydrocarbon, manufactured by 3M). A mini-emulsion was formed using the homogenizing module of a microfluidizer. An air motor using compressed air of about 40 psi sent the mixture through the homogenizing module. The whole mixture was sent through the homogenizing module six times. The final mixture was a translucent aqueous mini-emulsion of very light blue color. The aqueous mini-emulsion was then added to a 4-liter reactor. The reactor was evacuated three times and purged each time with tetrafluoroethylene gas. The oxygen content of the aqueous solution was about 20 ppm immediately prior to admitting the tetrafluoroethylene gas.

[0062] The reactor agitation speed was set at 700 rpm throughout the reaction. The aqueous mini-emulsion was heated from its jacket to a temperature about 83 degrees C. Then, tetrafluoroethylene gas was introduced to the pressure reactor to raise the pressure to 0.87 MPa. About 0.1 gram of ammonium persulfate pre-dissolved in 400 ml of deionized water was pumped into the reactor to start the reaction. The reaction temperature was maintained between 82 and 84 degrees C. throughout the polymerization. The tetrafluoroethylene pressure was maintained at about this initial value for a first reaction time of about 4 minutes. The tetrafluoroethylene supply was stopped and the reaction continued without more charge of tetrafluoroethylene to the reactor. The reaction pressure went down gradually from ˜0.87 MPa initially to about 0.2 MPa during the course of the next 172 minutes. Then, the reaction temperature was lowered to below 50 degrees C. and the reaction system was evacuated to atmosphere. The reaction yielded 2333 g of an aqueous dispersion of copolymer. The total weight percent copolymer obtained by precipitation and isolation was 9.7%. The average colloidal particle size was about 131 nm.

EXAMPLES 2-5

[0063] An aqueous mini-emulsion of polymer was prepared using a procedure similar to that of Example 1, but the polymerization was performed in a 30 liter reactor. Several reactions were performed at different reaction times and reactions pressures as shown in Table 1. In particular, an aqueous emulsion was prepared by pre-mixing 14,900 grams of deionized water, and 375 grams of 20% by weight of ammonium perfluoro octanoate (ammonium salt of perfluoro octanoic acid) aqueous solution, and 1200 grams of CF₂═CF—O—CF₂CF(CF₃)—O—CF₂CF₂—SO₂F monomer and 300 grams of Fluorinert® FC-77 (a perfluorinated hydrocarbon, manufactured by 3M). This mixture was homogenized to form a mini-emulsion using the same procedure described in Example 1. The aqueous mini-emulsion was then added to a 30 liter pressure reactor. The reactor was evacuated three times and purged each time with tetrafluoroethylene gas. The oxygen content of the aqueous solution was about 20 ppm immediately prior to admitting the tetrafluoroethylene gas. TABLE 1 Reaction Conditions for Example 2-5 Initial Final Total Weight Reac- 1st 2nd Reac- Weight Percent Average tion Reac- Reac- tion of dis- of solid Colloidal Pres- tion tion Pres- persion in dis- Particle sure Time Time sure product persion Size (MPa) (min) (min) (MPa) (kg) (%) (nm) Exam- 1.2 55 65 0.60 17.9 8.9 167 ple 2 Exam- 1.2 59 67 0.60 17.9 9.5 156 ple 3 Exam- 1.4 68 95 0.55 18.2 11.8 191 ple 5 Exam- 1.2 62 41 0.75 17.7 9.3 161 ple 5

[0064] The reactor agitation speed was set at 500 rpm throughout the reaction. The aqueous mini-emulsion was heated from its jacket to a temperature about 83 degrees C. Then, tetrafluoroethylene gas was introduced to the pressure reactor to raise the pressure to about that shown in Table 1 as the Initial Reaction Pressure. About 0.6 gram of ammonium persulfate was pre-dissolved in 100 ml of deionized water, added to an additional 400 ml of deionized water and pumped into the reactor to start the reaction. The reaction temperature was maintained between 82 and 84 degrees C. throughout the polymerization. The tetrafluoroethylene pressure was maintained at about this initial value for the first reaction time shown in Table 1. The tetrafluoroethylene supply was stopped and the reaction continued without more charge of tetrafluoroethylene to the reactor. The reaction pressure went down gradually from about the initial pressure shown in Table 1 to about the final pressure shown in Table 1 during the second reaction time shown in Table 1. Then, the reaction temperature was lowered to below 50 degrees C. and the reaction system was evacuated to atmosphere. The reactions yielded an aqueous dispersion of polymer, each characterized by the total weight of the dispersion, the weight percent of polymer in the dispersion, and an average colloidal particle size, as shown in Table 1.

[0065] Using the test procedure described above, the equivalent weight, degree of hydration, and 4 Point conductivity of Examples 1-5 was determined (Table 2). The conductivity is substantially higher, and the hydration lower, than the corresponding equivalent weights of prior art as described below in the Comparative Examples. Additionally, the high temperature conductivity of Example 2 and Comparative Example A were evaluated at two different temperatures and a range of relative humidities. Again, the conductivity of the inventive material is significantly higher at all temperatures and relative humidities as illustrated in Table 3.

COMPARATIVE EXAMPLE A

[0066] A Nafion® 112 membrane was purchased from Du Pont Co. It was tested as received to determine the equivalent weight and hydration. The conductivity was tested as described above except two measurements at 30 and 60 minutes were made in the machine direction on one piece of film, and a third measurement at 90 minutes was made in the transverse direction of a second piece of film. No significant different was observed between the conductivity of the two directions as expected from prior literature [see, for example, G. Blumenthal, M. Cappadonia, M. Lehman, “Investigation of the Proton Transport in Nafion® Membranes as a Function of Direction, Temperature and Relative Humidity”, Ionics, Volume 2, pg. 102-106(1996)]. The room temperature ionic conductivity was measured as described above, and the reported conductivity is the average of these three measurements (Table 2). The high temperature ionic conductivity was measured as described above except the ionomer that was brushed on the GDM was Nafion 1100 instead of that described above. The conductivity and hydration results are consistent with those widely reported in the literature for this commercial material [see, for example, T. Zawodinski, C. Derouin, S. Radzinski, R. Sherman, V. Smith, T. Springer and S. Gottesfeld, Journal of the Electrochemical Society, Volume 140, No. 4, 1041-1047 (1993)], confirming that the measurement technique is satisfactory.

COMPARATIVE EXAMPLE B-F

[0067] The data from Table 1 in WO 00/52060 for equivalent weights 1100, 980, 834 and 785 is reported directly as Comparative Example B, C, D, and E, respectively. Comparative Example F in Table 1 reports the data directly from inventive Example 9 of WO 00/52060. The conductivity and water uptake reported in WO 00/52060 were obtained using essentially the same procedure as that used here, so the data is directly comparable to the Example 1-5.

[0068] The data shown in Table 1 is presented graphically in FIG. 3 and FIG. 4 for conductivity and hydration, respectively. As shown by the data and the plot in FIG. 4, the hydration values for the inventive Examples having an equivalent weight between about 700 and about 900 are less than about 50%. For the inventive Example having an equivalent weight of less than about 700, the hydration value is about 120%. For comparable equivalent weights shown in the Comparative Examples, the degree of hydration of the inventive Examples is considerably lower. The ionomers of the inventive Examples are thus much better suited for high temperature or low humidity operation, for example in a fuel cell. TABLE 2 Equivalent Weight, Conductivity and Hydration of Inventive and Comparative Examples Mean Equivalent Room Weight Degree of Temperature (equivalents/ Hydration Conductivity gram) (%) (S/cm) Example 1 698 118.5 0.145* Example 2 810 42.3 0.251 Example 3 799 45.8 0.234 Example 4 862 32.0 0.173 Example 5 838 36.70 0.167 Comparative 1104 16.82 0.083 Example A Comparative 1100 25 0.0902 Example B Comparative 980 27.1 0.1193 Example C Comparative 834 53.1 0.1152 Example D Comparative 785 79.2 0.0791 Example E Comparative 1156 15 0.065 Example F

[0069] TABLE 3 High Temperature Conductivity Results at Various Temperatures and Relative Humidities Mean 2-Point Conductivity (S/cm) 80° C. 80° C. 120° C. 120° C. 20% RH 80% RH 10% RH 40% RH Comparative 0.003 0.044 0.001 0.0019 Example A Example 2 0.006 0.057 0.003 0.036

EXAMPLE 6 AND COMPARATIVE EXAMPLE G

[0070] Membrane electrode assemblies (MEAs) were made using the ionomer of Example 5, herein labeled Example 6. A corresponding Comparative Example using prior art, Comparative Example G was also prepared for comparison. The MEA of Example 7 was and prepared for testing as follows: the ionomer in its hydrolyzed and acidified form was first solubilized in ethanol to form a solution containing 10% ionomer. This solution was then impregnated into a 22.5 micron thick support of ePTFE according to the teachings of Bahar, et. al. in U.S. Pat. No. RE37,307. The ePTFE was fixed in a 10-in embroidery hoop. The ionomer solution was painted on both sides of the ePTFE and then dried with a hair drier to remove the solvent. The painting and drying steps were repeated 2 more times. The ePTFE and the embroidery hoop were then placed into a solvent oven at 180° C. for 8 minutes. The sample was then removed and allowed to cool to room temperature. One more coat of ionomer solution was painted on both sides. The sample was placed back into the oven at 180° C. for 8 minutes. The sample was then removed from the oven and taken off of the embroidery hoop. The ePTFE/ionomer composite membrane was transparent, indicating substantially complete impregnation of the support by the ionomer.

[0071] An electrode containing 0.4 mg Pt/cm² and available from W. L. Gore & Associates, Inc. as part of its MEA bearing the designation Primea® 5510 (available from Japan Gore-Tex Inc., Japan) was laminated to both sides of the composite membrane. The electrode was first laid down over an 0008 inch thick ePTFE bottom sheet. The composite membrane was then laid down over the electrode, and another electrode was laid down over the membrane. Then a 0.005 inch thick ePTFE top sheet was laid down over the electrode. The assembly was pressed at 160° C. at 15 tons of pressure for 3 minutes, then the top and bottom ePTFE sheets were peeled off and discarded.

[0072] Comparative Example G used a PRIMEA® membrane electrode assembly Series 5510, commercially available W. L. Gore and Associates. This assembly used the same electrodes as in Example 6 and a similar ePTFE reinforcement in the electrolyte. The only substantive difference between Example 6 and Comparative Example G, then, was the ionomer in the electrolyte.

[0073] Cells using the two MEAs were assembled anode side first. A silicone-coated fiberglass gasket 0.007 inches thick with an inner window of 52.5 cm² was first placed down on top of a quadruple serpentine graphite anode flow field available from Fuel Cell Technologies (50 cm², 8 bolt fuel cell test hardware available from Fuel Cell Technologies was used). On top of the silicone-coated fiberglass gasket was placed a 0.0012 inch thick OL-12 spacer (Mylar film available from DuPont) with an inner window of 52.5 cm² aligned with the inner window of the silicone-coated fiberglass gasket. Next, a single-sided Elat gas diffusion media (GDM) available from E-Tek, having a 52 cm² area and being about 0.014 to 0.015 inches thick, was placed inside the inner windows of the silicone-coated fiberglass gasket and the spacer with the carbon side facing up. Next, a 0.0012 inch thick OL-12 sub-gasket having an inner window of 45 cm² was placed on top of the GDM, followed by the MEA. This gasket reduced the active area of the cell to 0.45 cm . The above steps were repeated in the opposite order on top of the MEA. Once an MEA “sandwich” was created, a cathode flow field (same as the anode flow field described above) was placed on top. The bolts were lubricated with Krytox grease (available from DuPont) and tightened in a star pattern in 5 in-lb bolt increments until each bolt achieved 75 in-lb of torque. The components used yielded an active area compression of 150 to 200 psi.

[0074] The test station used was a Globe Tech gas unit with a Scribner 890 load. Three-liter humidification bottles were used on the anode and cathode, and all lines coming into the cell were heat traced (heated along their length). Once the cell was hooked up to the test station, the fuel gasses were applied (H₂ on anode at 1.3 stoichiometry and air on cathode at 2.0 stoichiometry). The cell was then set to 60° C. and both the anode and cathode bottles were set to 60° C. as well. The back pressure was kept at 0 psig on both sides. Once the temperatures came up to their respective set points, an automatic cycling program was run to “break in” the cell. The conditions for this cycling program are set forth in Table 3. TABLE 3 Start-up Procedure Time Anode Cathode Spent at Humidifi- Humidifi- Each cation cation Voltage Condition Temp. Temp. Anode (V) (min) (C.) (C.) RH* Cathode RH** 0.60 180 60 60 65%  85% 0.50 30 60 60 65%  85% 0.95 0.5 60 60 65%  85% 0.70 30 60 60 65%  85% 0.95 0.5 60 60 65%  85% 0.50 30 65 65 80% 100% 0.95 0.5 65 65 80% 100% 0.70 30 65 65 80% 100% 0.95 0.5 65 65 80% 100% 0.50 30 65 65 80% 100% 0.95 0.5 65 65 80% 100% 0.70 30 65 65 80% 100% 0.95 0.5 65 65 80% 100% 0.50 30 65 65 80% 100% 0.95 0.5 65 65 80% 100% 0.70 30 65 65 80% 100% 0.95 0.5 65 65 80% 100% 0.50 30 65 65 80% 100% 0.95 0.5 65 65 80% 100% 0.6 30 60 60 65%  85%

[0075] Subsequent to finishing the cycling in Table 3, the cell was set to 80° C. cell temperature, 83° C. anode humidification, 51° C. cathode humidification, and 7 psig back pressure on both the anode and cathode. This yielded an anode inlet relative humidity (RH) of 75% and a cathode inlet RH of 25%, assuming the anode humidifiers are 65% efficient and the cathode humidifiers are 85% efficient. Once the temperatures and pressures reached their respective set points, an automatic “sensitivity protocol” was begun to test the MEA at various humidities. The “sensitivity protocol” is a program designed to determine how an MEA will respond to changing humidity conditions. It is particularly designed to show the effects of cell operation in relatively dry conditions. TABLE 4 Fuel Cell Humidity Sensitivity Protocol and Voltage Results Anode Cathode Comparative Exam- Humidity Humidity Example G ple 7 Temp. Anode Temp.** Cathode Mean Mean Step (C.) RH* (C.) RH** Voltage Voltage 1 83  75% 51 25% 0.685 0.686 2 86 100% 65  50% 0.684 0.682 3 86 100% —† dry 0.658 0.682 4 83  75% —† dry 0.596 0.606 5 83  50% —† dry 0.552 0.570

[0076] The protocol shown in Table 4 was followed. For each set of humidity conditions in Table 4, the cell was operated for two hours at a constant current density of 800 mA/cm². The voltage during this time was recorded, and the mean two-hour voltage-time data was calculated and recorded. Following the two-hour constant current hold, a polarization curve was recorded (not reported here). The polarization curve was obtained by measuring the steady state voltage after 10 or 20 minutes (longer time for dry cathode conditions) following sequential steps to each of the following current densities: 0.8, 1.0, 1.2, 1.4 A/cm². Then the current density was stepped to 0.8 A/cm² and the open circuit voltage (i.e., no load applied to the cell) was measured after 1.5 minutes. Then the rest of the polarization curve was obtained by measuring the steady state voltage after 10 or 20 minutes (longer time for dry cathode conditions) following sequential steps to 0.6, 0.4, 0.2 A/cm². Finally, the steady state voltage was measured after 5 or 13 minutes (longer time for dry cathode condition) at 0.1 A/cm². The temperatures of the anode and cathode humidity bottles were then changed to the next condition shown in Table 4 to achieve the next RH conditions. An 800 mA/cm² constant current was applied, the voltage-time data recorded, a mean voltage calculated, and a polarization curve taken as before. This procedure was repeated for each step in protocol shown in Table 4

[0077] The average voltages observed for cells made from the inventive ionomers when tested under dry conditions, for example, step 3, 4 and 5 in Table 4, are significantly greater than the voltages previously obtainable using known ionomers such as that in Comparative Example G. The dramatic improvement obtained using the present invention under the drier conditions demonstrates the utility of the ionomer when it comprises part of the electrolyte. 

We claim:
 1. A fluorinated ionomer comprising a substantially fluorinated backbone with pendant groups attached thereto, said pendant groups represented by the formula

where X is F, Cl or Br or mixtures thereof; n is an integer equal to one or two; R_(f) and R_(f′) are independently selected from the group of F, Cl, perfluoroalkyl radical, and chloroperfluoroalkyl radical; Y is an acid group or a functional group convertible to acid group; a is zero or an integer greater than zero; and b is an integer greater than zero; wherein said ionomer has an equivalent weight between about 600 and about 950; and wherein said ionomer has a room temperature ionic conductivity of greater than about 0.13 S/cm when measured on an acid form of a membrane of said ionomer.
 2. A fluorinated ionomer as defined in claim 1 where a is equal to zero; b is equal to 1; n is equal to one; R_(f) and R_(f′) are both Fluorine and Y is chosen from the group consisting of SO₃Z; SO₂N(R₁R_(1′)), SO₂NR₁SO₂R₂, CO₂Z, PO(OR₁)₂; wherein Z is H, or any combination of ammonium ion, metallic ions or organoammonium ions; R₁ and R_(1′) are independently selected from the group consisting of H, an alkyl group with carbon number from 1 to 10, or a partially fluorinated alkyl group with a carbon number of 1-10, and R₂ is a perfluorinated alkyl chain with carbon number from 1 to 8, or a perfluoroalkyl group terminated with Y as it is defined above.
 3. A fluorinated ionomer as defined in claim 2 where Y is SO₃H.
 4. A fluorinated ionomer as defined in claim 1 where a is equal to zero; b is equal to 1; n is equal to one; R_(f) and R_(f′) are both F; and Y is chosen from the group consisting of SO₂W, where W is selected from the group consisting of F, Cl, or Br; and COOR; where R is an alkyl group with carbon number from 1 to
 20. 5. A fluorinated ionomer of claim 4 where Y is SO₂F.
 6. A fluorinated ionomer as defined in claim 1 wherein said equivalent weight is about
 900. 7. A fluorinated ionomer as defined in claim 1 wherein said equivalent weight is about
 850. 8. A fluorinated ionomer as defined in claim 1 wherein said equivalent weight is about
 800. 9. A fluorinated ionomer as defined in claim 1 wherein said equivalent weight is about
 750. 10. A fluorinated ionomer as defined in claim 1 wherein said equivalent weight is about
 700. 11. A fluorinated ionomer as defined in claim 1 wherein said equivalent weight is about
 650. 12. A process for making a fluorinated polymer comprising the steps of: a) forming a mini-emulsion of a mixture of deionized water, a perfluorinated surfactant, optionally dissolved in an aqueous solution, a liquid perfluorinated hydrocarbon having a molecular weight below 2000 and an ionomeric monomer; b) pressurizing said emulsion in an agitated reactor with at least one substantially fluorinated alkene gas; c) initiating polymerization with a free radical initiator in said reactor; d) maintaining a known pressure of the substantially fluorinated alkene gas for a period of time; and e) recovering said fluorinated polymer.
 13. The process of claim 12 wherein the substantially fluorinated alkene is tetrafluoroethylene.
 14. The process of claim 13 where the perfluorinated surfactant is ammonium perfluoro octanoate.
 15. The process of claim 14 wherein the ionomeric monomer has the formula CF₂═CF—O—CF₂CF(CF₃)—O—CF₂CF ₂—SO₂F.
 16. The process of claim 15 wherein the initiator is ammonium persulfate.
 17. The process of claim 16 wherein the concentration of ammonium perfluoro octanoate in aqueous solution is less than about 0.5 percent by weight; the concentration of the ionomeric monomer is less than about 10 percent by weight, the concentration of liquid hydrocarbon with molecular weight less than 2000 is less than about 5% by weight, and the concentration of the ammonium persulfate is less than about 0.01 percent by weight.
 18. A product produced by a process comprising the steps of: a) forming a mini-emulsion of a mixture of deionized water, a perfluorinated surfactant, optionally dissolved in an aqueous solution, a liquid perfluorinated hydrocarbon having a molecular weight below 2000 and an ionomeric monomer; b) pressurizing said emulsion in an agitated reactor with at least one substantially fluorinated alkene gas; c) initiating polymerization with a free radical initiator in said reactor; and d) maintaining a known pressure of the substantially fluorinated alkene gas for a period of time.
 19. The product of claim 18 wherein said product has an equivalent weight between about 600 and about 950, and wherein the ionic conductivity of the acid form of a membrane hydrated at room temperature prepared from said product is greater than about 0.13 S/cm at room temperature.
 20. A membrane comprising the fluorinated ionomer of claim
 1. 21. A membrane comprising the fluorinated ionomer of claim
 2. 22. A membrane comprising the fluorinated ionomer of claim
 3. 23. A membrane comprising the fluorinated ionomer of claim
 4. 24. A membrane comprising the fluorinated ionomer of claim
 5. 25. A membrane comprising a porous support and the fluorinated ionomer of claim 1 impregnated within said porous support.
 26. A membrane comprising a porous support and the fluorinated ionomer of claim 2 impregnated within said porous support.
 27. A membrane comprising a porous support and the fluorinated ionomer of claim 3 impregnated within said porous support.
 28. A membrane comprising a porous support and the fluorinated ionomer of claim 4 impregnated within said porous support.
 29. A membrane comprising a porous support and the fluorinated ionomer of claim 5 impregnated within said porous support.
 30. A membrane as defined in claim 25 wherein said porous support is expanded polytetrafluoroethylene.
 31. A membrane as defined in claim 25 wherein said fluorinated ionomer substantially completely impregnates said porous support.
 32. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 25. 33. A membrane as defined in claim 26 wherein said porous support is expanded polytetrafluoroethylene.
 34. A membrane as defined in claim 26 wherein said fluorinated ionomer substantially completely impregnates said porous support.
 35. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 26. 36. A membrane as defined in claim 27 wherein said porous support is expanded polytetrafluoroethylene.
 37. A membrane as defined in claim 27 wherein said fluorinated ionomer substantially completely impregnates said porous support.
 38. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 27. 39. A membrane as defined in claim 28 wherein said porous support is expanded polytetrafluoroethylene.
 40. A membrane as defined in claim 28 wherein said fluorinated ionomer substantially completely impregnates said porous support.
 41. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 28. 42. A membrane as defined in claim 29 wherein said porous support is expanded polytetrafluoroethylene.
 43. A membrane as defined in claim 29 wherein said fluorinated ionomer substantially completely impregnates said porous support.
 44. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 29. 45. A membrane electrode assembly whereby either the anode, cathode or both comprises the fluorinated ionomer of claim
 1. 46. A membrane electrode assembly whereby either the anode, cathode or both comprises the fluorinated ionomer of claim
 2. 47. A membrane electrode assembly whereby either the anode, cathode or both comprises the fluorinated ionomer of claim
 3. 48. A membrane electrode assembly whereby either the anode, cathode or both comprises the fluorinated ionomer of claim
 4. 49. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 20. 50. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 21. 51. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 22. 52. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 24. 53. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 25. 54. A fuel cell comprising the membrane electrode assembly of claims
 49. 55. A fuel cell comprising the membrane electrode assembly of claims
 50. 56. A fuel cell comprising the membrane electrode assembly of claims
 51. 57. A fuel cell comprising the membrane electrode assembly of claims
 52. 58. A fuel cell comprising the membrane electrode assembly of claims
 53. 59. A fuel cell comprising the membrane electrode assembly of claims
 54. 60. An electrolytic cell comprising the membrane electrode assembly of claim
 49. 61. A fluorinated ionomer comprising a substantially fluorinated backbone with pendant groups attached thereto, said pendant groups represented by the formula

where X is F, Cl or Br or mixtures thereof; n is an integer equal to one or two; R_(f) and R_(f′) are independently selected from the group of F, Cl, perfluoroalkyl radical, and chloroperfluoroalkyl radical; Y is an acid group or an acid derivative easily converted to an acid group; a is zero or an integer greater than zero; and b is an integer greater than zero; wherein said ionomer has an equivalent weight between about 700 and about 900 and a degree of hydration at room temperature that is less than about 50%.
 62. The fluorinated ionomer of claim 61 wherein the equivalent weight is about 800 and the degree of hydration is between about 40% and about 45% at room temperature.
 63. The fluorinated ionomer of claim 61 where the equivalent weight is between about 810 and about 860 and the degree of hydration is between about 32% and about 42% at room temperature.
 64. A fluorinated ionomer comprising a substantially fluorinated backbone with pendant groups attached thereto, said pendant groups represented by the formula

where X is F, Cl or Br or mixtures thereof; n is an integer equal to one or two; R_(f) and R_(f′) are independently selected from the group of F, Cl, perfluoroalkyl radical, and chloroperfluoroalkyl radical; Y is an acid group or an acid derivative easily converted to an acid group; a is zero or an integer greater than zero; and b is an integer greater than zero; wherein the equivalent weight is below about 700 and the degree of hydration is less than about 200% at room temperature.
 65. A fluorinated ionomer as defined in claim 64 wherein said degree of hydration is about 120% at room temperature.
 66. A membrane comprising the fluorinated ionomer of claim
 61. 67. A membrane comprising the fluorinated ionomer of claim
 62. 68. A membrane comprising the fluorinated ionomer of claim
 63. 69. A membrane comprising the fluorinated ionomer of claim
 64. 70. A membrane comprising a porous support and the fluorinated ionomer of claim 61 impregnated within said porous support.
 71. A membrane comprising a porous support and the fluorinated ionomer of claim 62 impregnated within said porous support.
 72. A membrane comprising a porous support and the fluorinated ionomer of claim 63 impregnated within said porous support.
 73. A membrane comprising a porous support and the fluorinated ionomer of claim 64 impregnated within said porous support.
 74. A membrane as defined in claim 70 wherein said fluorinated ionomer substantially completely impregnates said porous support.
 75. A membrane as defined in claim 71 wherein said fluorinated ionomer substantially completely impregnates said porous support.
 76. A membrane as defined in claim 72 wherein said fluorinated ionomer substantially completely impregnates said porous support.
 77. A membrane as defined in claim 73 wherein said fluorinated ionomer substantially completely impregnates said porous support.
 78. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 70. 79. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 71. 80. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 72. 81. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 73. 82. A membrane as defined in claim 70 wherein said porous support is expanded polytetrafluoroethylene.
 83. A membrane as defined in claim 71 wherein said porous support is expanded polytetrafluoroethylene.
 84. A membrane as defined in claim 72 wherein said porous support is expanded polytetrafluoroethylene.
 85. A membrane as defined in claim 73 wherein said porous support is expanded polytetrafluoroethylene.
 86. A membrane electrode assembly comprising an anode, a cathode and a membrane, wherein at least one of said anode and said cathode comprises the fluoroinated ionomer of claim
 61. 87. A membrane electrode assembly comprising an anode, a cathode and a membrane, wherein at least one of said anode and said cathode comprises the fluorinated ionomer of claim
 62. 88. A membrane electrode assembly comprising an anode, a cathode and a membrane, wherein at least one of said anode and said cathode comprises the fluorinated ionomer of claim
 63. 89. A membrane electrode assembly comprising an anode, a cathode and a membrane, wherein at least one of said anode and said cathode comprises the fluorinated ionomer of claim
 64. 90. A membrane electrode assembly comprising an anode and a cathode sandwiching the membrane of claim
 70. 91. A fuel cell comprising the membrane electrode assembly of claim
 90. 92. An electrolytic cell comprising the membrane electrode assembly of claim
 90. 